Synthesis, Crystal Structure, and Optical Properties of a Trinuclear Zinc(II) Complex with Rhodamine B
نویسندگان
چکیده
A heteroleptic homotrinuclear complex, [Zn3(valhydr)2(RhB)2(EtOH)2](ClO4)2 (H2valhydr = 1,2-bis(2-hydroxy-3-methoxybenzylidene)hydrazine, RhB rhodamine B), was synthesized and structurally characterized by X-ray diffraction on single crystal. In the centrosymmetric zinc ions are positioned in a linear manner. The external pentacoordinated with distorted square pyramidal stereochemistry, while central ion presents an elongated octahedral geometry. Luminescent properties of complex were investigated solid state solution.
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ژورنال
عنوان ژورنال: Crystals
سال: 2022
ISSN: ['2073-4352']
DOI: https://doi.org/10.3390/cryst12121813